Photocatalytic process using magnesium oxide nanoparticles for amoxicillin removal from aqueous solution
نویسندگان
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Ashrafi, Seyed Davoud
Department of Environmental Health, School of Health, Guilan University of Medical Sciences, Rasht, Iran
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Bazrafshan, Edris
Health Sciences Research Center, Torbat Heydariyeh University of Medical Sciences, Torbat Heydariyeh, Iran
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Kamani, Hossein
Student Research Committee, Zahedan University of Medical Sciences, Zahedan, Iran
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Kord Mostafapour, Ferdous
1. Dimitrakopoulou D, Rethemiotaki I, Frontistis Z, Xekoukoulotakis NP, Venieri D, Mantzavinos D. Degradation, mineralization and antibiotic inactivation of amoxicillin by UV-A/TiO2 photocatalysis. Journal of Environmental Management. 2012;98:168-74. 2. Liu H, Liu W, Zhang J, Zhang C, Ren L, Li Y. Removal of cephalexin from aqueous solutions by original and Cu (II)/Fe (III) impregnated activated carbons developed from lotus stalks Kinetics and equilibrium studies. Journal of hazardous materials. 2011;185:1528-35. 3. Elmolla ES, Chaudhuri M. Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis. Desalination. 2010;252(1-3):46-52. 4. Kakavandi B, Rezaei Kalantary R, Jonidi Jafari A, Esrafily A, Gholizadeh A, Azari A. Efficiency of powder activated carbon magnetized by Fe3O4 nanoparticles for amoxicillin removal from aqueous solutions: Equilibrium and kinetic studies of adsorption process. Iranian Journal of Health and Environment. 2014;7(1):21-34. 5. Jung YJ, Kim WG, Yoon Y, Kang J-W, Hong YM, Kim HW. Removal of amoxicillin by UV and UV/H2O2 processes. Science of the Total Environment. 2012;420:160-7. 6. Fazlzadeh M, Gulshan S, Bohloul A, Rezaei M. Evaluation of Electro-Fenton Process in Amoxicillin Removal from Aqueous Solutions. Journal of Health. 2016;7(3):276-87. 7. Alahabadi A, Moussavi G, Yaghmaeian K, Karemisany H. Adsorption potential of the granular activated carbon for the removal of amoxicillin from water. 2014. 8. Samadi MT, Shokoohi R, Araghchian M, Tarlani Azar M. Amoxicillin Removal from Aquatic Solutions Using Multi-Walled Carbon Nanotubes. Journal of Mazandaran University of Medical Sciences. 2014;24(117):103-15. 9. Javier Benitez F, Acero JL, Real FJ, Roldán G, Rodriguez E. Ultrafiltration and nanofiltration membranes applied to the removal of the pharmaceuticals amoxicillin, naproxen, metoprolol and phenacetin from water. Journal of Chemical Technology and Biotechnology. 2011;86(6):858-66. 10. Kermani M, Bahrami Asl F, Farzadkia M, Esrafili A, Salahshur Arian S, Arfaeinia H, et al. Degradation efficiency and kinetic study of metronidazole by catalytic ozonation process in presence of mgo nanoparticles. The Journal of Urmia University of Medical Sciences. 2013;24(10):839-50. 11. Elmolla ES, Chaudhuri M. Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process. Journal of hazardous materials. 2010;173(1-3):445-9. 12. Mohammadi R, Massoumi B, Rabani M. Photocatalytic decomposition of amoxicillin trihydrate antibiotic in aqueous solutions under UV irradiation using Sn/TiO2 nanoparticles. International Journal of Photoenergy. 2012;2012. 13. Su S, Guo W, Yi C, Leng Y, Ma Z. Degradation of amoxicillin in aqueous solution using sulphate radicals under ultrasound irradiation. Ultrasonics sonochemistry. 2012;19(3):469-74. 14. Mohamadi L, Bazrafshan E, Noroozifar M, Ansari-Moghaddam A. Ethyl benzene removal from aqueous environments by catalytic ozonation process using MgO nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(143):129-44. 15. Bahrami-asl F, Kermani M, Salahshour-Arian S, Mollamahmoudi-Abadi M, Zeynalzadeh D. Catalytic ozonation of azo dye Reactive Red 120 in the presence of MgO nanoparticles. Journal of Health in the Field. 2017;2(2). 16. Kıdak R, Doğan Ş. Medium-high frequency ultrasound and ozone based advanced oxidation for amoxicillin removal in water. Ultrasonics sonochemistry. 2018;40:131-9. 17. Sui M, Xing S, Sheng L, Huang S, Guo H. Heterogeneous catalytic ozonation of ciprofloxacin in water with carbon nanotube supported manganese oxides as catalyst. Journal of hazardous materials. 2012;227:227-36. 18. Mohammadi L, Bazrafshan E, Noroozifar M, Ansari-Moghaddam A. Application of heterogeneous catalytic ozonation process with magnesium oxide nanoparticles for Toluene degradation in aqueous environments. Health Scope. 2016;5(4). 19. Kamani H, Nasseri S, Khoobi M, Nabizadeh Nodehi R, Mahvi AH. Sonocatalytic degradation of humic acid by N-doped TiO2 nano-particle in aqueous solution. Journal of environmental health science & engineering. 2016;14:3-. 20. Bazrafshan E, Noorzaei S, KordMostafapour F. Photocatalytic degradation of aniline in aqueous solutions using magnesium oxide nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(139):126-36. 21. Dehghani MH, Faraji M, Mohammadi A, Kamani H. Optimization of fluoride adsorption onto natural and modified pumice using response surface methodology: Isotherm, kinetic and thermodynamic studies. Korean Journal of Chemical Engineering. 2017;34(2):454-62. 22. Jaafari J, Seyedsalehi M, Safari GH, Ebrahimi Arjestan M, Barzanouni H, Ghadimi S, et al. Simultaneous biological organic matter and nutrient removal in an anaerobic/anoxic/oxic (A2O) moving bed biofilm reactor (MBBR) integrated system. International Journal of Environmental Science and Technology. 2017;14(2):291-304. 23. Xie Y, Chen L, Liu R. Oxidation of AOX and organic compounds in pharmaceutical wastewater in RSM-optimized-Fenton system. Chemosphere. 2016;155:217-24. 24. Xiao J, Xie Y, Cao H. Organic pollutants removal in wastewater by heterogeneous photocatalytic ozonation. Chemosphere. 2015;121:1-17. 25. Kamani H, Bazrafshan E, Ashrafi SD, Sancholi F. Efficiency of Sono-nano-catalytic Process of Tio2 Nano-particle in Removal of Erythromycin and Metronidazole from Aqueous Solution. Journal of Mazandaran University of Medical Sciences. 2017;27(151):140-54. 26. Samarghandi M, Asgari G, Chavoshi S, Ghavami Z, Mehralipour J. Performance of Catalytic Ozonation by Fe/MgO Nanoparticle for Degradation of Cefazolin from Aqueous Environments. Journal of Mazandaran University of Medical Sciences. 2015;25(128):77-90. 27. Malakootian M, Hashemi Cholicheh M. Efficacy of Photocatalytic Processes Using Silica and Zirconia Nanoparticles in the Bivalent Nickel Removal of Aqueous Solutions and Determining the Optimum Removal Conditions. Journal of Mazandaran University of Medical Sciences.2012;22(93):87-96. 28. Safari G, Hoseini M, Kamali H, Moradirad R, Mahvi A. Photocatalytic degradation of tetracycline antibiotic from aqueous solutions using UV/TiO2 and UV/H2O2/TiO2. 2014. 29. Taghi Ghaneian M, Ebrahimi A, Salimi J, Khosravi R, Fallahzadeh RA, Amrollahi M, et al. Photocatalytic Degradation of 2, 4-Dichlorophenoxyacetic acid from Aqueous Solutions Using In2O3 Nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(137):159-70.
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Norabadi, Elham
1. Dimitrakopoulou D, Rethemiotaki I, Frontistis Z, Xekoukoulotakis NP, Venieri D, Mantzavinos D. Degradation, mineralization and antibiotic inactivation of amoxicillin by UV-A/TiO2 photocatalysis. Journal of Environmental Management. 2012;98:168-74. 2. Liu H, Liu W, Zhang J, Zhang C, Ren L, Li Y. Removal of cephalexin from aqueous solutions by original and Cu (II)/Fe (III) impregnated activated carbons developed from lotus stalks Kinetics and equilibrium studies. Journal of hazardous materials. 2011;185:1528-35. 3. Elmolla ES, Chaudhuri M. Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis. Desalination. 2010;252(1-3):46-52. 4. Kakavandi B, Rezaei Kalantary R, Jonidi Jafari A, Esrafily A, Gholizadeh A, Azari A. Efficiency of powder activated carbon magnetized by Fe3O4 nanoparticles for amoxicillin removal from aqueous solutions: Equilibrium and kinetic studies of adsorption process. Iranian Journal of Health and Environment. 2014;7(1):21-34. 5. Jung YJ, Kim WG, Yoon Y, Kang J-W, Hong YM, Kim HW. Removal of amoxicillin by UV and UV/H2O2 processes. Science of the Total Environment. 2012;420:160-7. 6. Fazlzadeh M, Gulshan S, Bohloul A, Rezaei M. Evaluation of Electro-Fenton Process in Amoxicillin Removal from Aqueous Solutions. Journal of Health. 2016;7(3):276-87. 7. Alahabadi A, Moussavi G, Yaghmaeian K, Karemisany H. Adsorption potential of the granular activated carbon for the removal of amoxicillin from water. 2014. 8. Samadi MT, Shokoohi R, Araghchian M, Tarlani Azar M. Amoxicillin Removal from Aquatic Solutions Using Multi-Walled Carbon Nanotubes. Journal of Mazandaran University of Medical Sciences. 2014;24(117):103-15. 9. Javier Benitez F, Acero JL, Real FJ, Roldán G, Rodriguez E. Ultrafiltration and nanofiltration membranes applied to the removal of the pharmaceuticals amoxicillin, naproxen, metoprolol and phenacetin from water. Journal of Chemical Technology and Biotechnology. 2011;86(6):858-66. 10. Kermani M, Bahrami Asl F, Farzadkia M, Esrafili A, Salahshur Arian S, Arfaeinia H, et al. Degradation efficiency and kinetic study of metronidazole by catalytic ozonation process in presence of mgo nanoparticles. The Journal of Urmia University of Medical Sciences. 2013;24(10):839-50. 11. Elmolla ES, Chaudhuri M. Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process. Journal of hazardous materials. 2010;173(1-3):445-9. 12. Mohammadi R, Massoumi B, Rabani M. Photocatalytic decomposition of amoxicillin trihydrate antibiotic in aqueous solutions under UV irradiation using Sn/TiO2 nanoparticles. International Journal of Photoenergy. 2012;2012. 13. Su S, Guo W, Yi C, Leng Y, Ma Z. Degradation of amoxicillin in aqueous solution using sulphate radicals under ultrasound irradiation. Ultrasonics sonochemistry. 2012;19(3):469-74. 14. Mohamadi L, Bazrafshan E, Noroozifar M, Ansari-Moghaddam A. Ethyl benzene removal from aqueous environments by catalytic ozonation process using MgO nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(143):129-44. 15. Bahrami-asl F, Kermani M, Salahshour-Arian S, Mollamahmoudi-Abadi M, Zeynalzadeh D. Catalytic ozonation of azo dye Reactive Red 120 in the presence of MgO nanoparticles. Journal of Health in the Field. 2017;2(2). 16. Kıdak R, Doğan Ş. Medium-high frequency ultrasound and ozone based advanced oxidation for amoxicillin removal in water. Ultrasonics sonochemistry. 2018;40:131-9. 17. Sui M, Xing S, Sheng L, Huang S, Guo H. Heterogeneous catalytic ozonation of ciprofloxacin in water with carbon nanotube supported manganese oxides as catalyst. Journal of hazardous materials. 2012;227:227-36. 18. Mohammadi L, Bazrafshan E, Noroozifar M, Ansari-Moghaddam A. Application of heterogeneous catalytic ozonation process with magnesium oxide nanoparticles for Toluene degradation in aqueous environments. Health Scope. 2016;5(4). 19. Kamani H, Nasseri S, Khoobi M, Nabizadeh Nodehi R, Mahvi AH. Sonocatalytic degradation of humic acid by N-doped TiO2 nano-particle in aqueous solution. Journal of environmental health science & engineering. 2016;14:3-. 20. Bazrafshan E, Noorzaei S, KordMostafapour F. Photocatalytic degradation of aniline in aqueous solutions using magnesium oxide nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(139):126-36. 21. Dehghani MH, Faraji M, Mohammadi A, Kamani H. Optimization of fluoride adsorption onto natural and modified pumice using response surface methodology: Isotherm, kinetic and thermodynamic studies. Korean Journal of Chemical Engineering. 2017;34(2):454-62. 22. Jaafari J, Seyedsalehi M, Safari GH, Ebrahimi Arjestan M, Barzanouni H, Ghadimi S, et al. Simultaneous biological organic matter and nutrient removal in an anaerobic/anoxic/oxic (A2O) moving bed biofilm reactor (MBBR) integrated system. International Journal of Environmental Science and Technology. 2017;14(2):291-304. 23. Xie Y, Chen L, Liu R. Oxidation of AOX and organic compounds in pharmaceutical wastewater in RSM-optimized-Fenton system. Chemosphere. 2016;155:217-24. 24. Xiao J, Xie Y, Cao H. Organic pollutants removal in wastewater by heterogeneous photocatalytic ozonation. Chemosphere. 2015;121:1-17. 25. Kamani H, Bazrafshan E, Ashrafi SD, Sancholi F. Efficiency of Sono-nano-catalytic Process of Tio2 Nano-particle in Removal of Erythromycin and Metronidazole from Aqueous Solution. Journal of Mazandaran University of Medical Sciences. 2017;27(151):140-54. 26. Samarghandi M, Asgari G, Chavoshi S, Ghavami Z, Mehralipour J. Performance of Catalytic Ozonation by Fe/MgO Nanoparticle for Degradation of Cefazolin from Aqueous Environments. Journal of Mazandaran University of Medical Sciences. 2015;25(128):77-90. 27. Malakootian M, Hashemi Cholicheh M. Efficacy of Photocatalytic Processes Using Silica and Zirconia Nanoparticles in the Bivalent Nickel Removal of Aqueous Solutions and Determining the Optimum Removal Conditions. Journal of Mazandaran University of Medical Sciences.2012;22(93):87-96. 28. Safari G, Hoseini M, Kamali H, Moradirad R, Mahvi A. Photocatalytic degradation of tetracycline antibiotic from aqueous solutions using UV/TiO2 and UV/H2O2/TiO2. 2014. 29. Taghi Ghaneian M, Ebrahimi A, Salimi J, Khosravi R, Fallahzadeh RA, Amrollahi M, et al. Photocatalytic Degradation of 2, 4-Dichlorophenoxyacetic acid from Aqueous Solutions Using In2O3 Nanoparticles. Journal of Mazandaran University of Medical Sciences. 2016;26(137):159-70.
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pirasteh, khadijeh
Student Research Committee, Zahedan University of Medical Sciences, Zahedan, Iran
چکیده مقاله:
Background & Aim: Excessive consumption of antibiotics and their incomplete metabolization in human and animals, as well as inadequate removal by conventional waste water system leads to the release of these chemicals into the environment. Antibiotics have adverse effects including bacterial resistance, digestive disorders and genotoxic. Therefore the aim of this study was to survey amoxicillin removal by photocatalytic process using magnesium oxide nanoparticles.
Methods: This experimental study was carried in the form of batch in the laboratory. In this study, independent parameters including pH (3, 7, 11), magnesium oxide nanoparticles concentration (250, 500, 750 ml/L) and reaction time (30, 60, 90) were evaluated for getting high mineralization efficiency. In order to achieve the optimal experimental conditions, response surface methodology (RSM) model was designed and applied. Analysis of variance (ANOVA) was used for data analysis.
Results: According to the obtained results, the effect of independent parameters including pH and nanoparticles on removal process was significant (p-value<0.05) and the highest efficiency for mineralization of amoxicillin was achieved 79.0% in optimum condition pH: 11, nanoparticle concentration: 500 mg/L and reaction time: 90 min.
Conclusion: Photocatalytic process using magnesium oxide can be considered as an effective method for amoxicillin removal from aqueous solution.
